分子結構與光譜
Molecular Structure and Spectroscopy
學期
109-1
學分
2
學分
當期課號
5963
永久課號
IMO5146
開課單位
應用化學系分子科學碩博班
授課教師
江幡孝之
校區
光復
類別
選修
上課時間表
| 節 | 週二 |
|---|---|
3 10:10–11:00 | 分子結構與光譜 SB522 2 節連堂 |
4 11:10–12:00 |
* 根據陽明交大上課時間表所列
概述
The class is aimed to learn the molecular structures, electronic states, vibrations and various spectroscopic methods (absorption, emission, light scattering) to investigate them. The photochemistry of photo-excited molecules is also discussed.
先修科目
Knowledge of physics of high school and basic part of quantum mechanics and quantum chemistry
教學方式
Lecture will be given by a power point
評分方式
Report 40%, Final exam 60%
週次計畫
| 週次 | 主題 |
|---|---|
| 第 1 週 | Introduction of time-dependent and time-independent Shrödinger equation |
| 第 2 週 | Perturbation theory (time-independent) and its application |
| 第 3 週 | Electronic structure and state of molecules from diatomic molecules to polyatomic molecules part-1 |
| 第 4 週 | Electronic structure and state of molecules from diatomic molecules to polyatomic molecules part-2 |
| 第 5 週 | Vibrations part-1. A diatomic molecule |
| 第 6 週 | Vibrations part-2. Normal mode of a polyatomic molecule |
| 第 7 週 | Vibrations part-3. Anharmonicity and anharmonic coupling - Fermi resonance |
| 第 8 週 | Interaction between molecules and light (electromagnetic field) part-1. Time-dependent perturbation theory and dipole transition moment |
| 第 9 週 | Interaction between molecules and light (electromagnetic field) part-2. Absorption and emission: Einstein Coefficient |
| 第 10 週 | Interaction between molecules and light (electromagnetic field) part-3. Multi-photon process |
| 第 11 週 | Electronic and vibrational spectra part-1. B.O. approximation and Franck-Condon principle |
| 第 12 週 | Electronic and vibrational spectra part-2. Vibronic coupling |
| 第 13 週 | Electronic and vibrational spectra part-3. IR and Raman transitions |
| 第 14 週 | Photophysics and photochemistry of the excited state molecules part-1. Jablonski diagram, Internal conversion (IC), Intersystem crossing (ISC) |
| 第 15 週 | Photophysics and photochemistry of the excited state molecules part-2. Intramolecular vibrational energy redistribution (IVR) |
| 第 16 週 | Final exam. |
| 第 17 週 | Spare day (flexible) |
| 第 18 週 | Spare day (flexible) |
教科書
A resume (pdf-file) will be uploaded on the web page. Students are requested to download the files. (1) P. Atkins and J. de Pauls, "Physical Chemistry", Oxford Univ. Press. (2) P. Atkins, "Molecular Quantum Mechanics", Oxford Univ. Press.
Office Hours
- 時間
- Any available time
- 聯絡方式
- tebata@nctu.edu.tw