物理化學(2)
Physical Chemistry(II)
學期
113-1
學分
3
學分
當期課號
910261
永久課號
SESE20040
開課單位
系統工程與科技學士學位學程
授課教師
黃文鍵
類別
必修
上課時間表
| 節 | 週二 | 週五 |
|---|---|---|
6 14:20–15:10 | 物理化學(2) 2 節連堂 | |
7 15:30–16:20 | ||
A 18:30–19:20 | 物理化學(2) |
* 根據陽明交大上課時間表所列
概述
學習基本的量子力學觀念並了解量子力學在微觀化學體系的應用,作為大四以後進階課程的基礎。
先修科目
普通化學、物理化學(1)
教學方式
課堂解說、教學投影片
評分方式
平時作業(30%) 期中考(30%) 期末考(40%)
課程大綱
- Introduction to Physical Chemistry
- Electromagnetic Radiation and the Old Quantum Theory
- Bohr's Atomic Theory
- The Foundations of Quantum Mechanics
- Schrodinger's Wave Mechanics
- Schrodinger's Wave Mechanics
- Quantum-Mechanical Postulates
- Quantum-Mechanical Postulates
- Quantum Mehanics of Some Simple Systems
- Mid-term Exam
- Quantum Mechanics of Hydrogenlike Atoms
- Quantum Mechanics of Hydrogenlike Atoms
- Physical Significance of the Orbital Quantum Numbers
- Angular Momentum and Magnetic Moment
- The Rigid Linear Rotor Spin Quantum Numbers
- Many-Electron Atoms
- Approximation Method in Quantum Mechanics
- Approximation Method in Quantum Mechanics
- Final Exam
週次計畫
| 週次 | 主題 |
|---|---|
| 第 1 週 | Introduction to Physical Chemistry |
| 第 1 週 | Introduction to Physical Chemistry |
| 第 2 週 | Electromagnetic Radiation and the Old Quantum Theory 1. Simple Harmonic Motion 2. Plane Waves and Standing Waves 3. Blackbody Radiation 4. Einstein and the Quantization of Radiation 5. Zero-Point Energy |
| 第 2 週 | Electromagnetic Radiation and the Old Quantum Theory 1. Simple Harmonic Motion 2. Plane Waves and Standing Waves 3. Blackbody Radiation 4. Einstein and the Quantization of Radiation 5. Zero-Point Energy |
| 第 3 週 | Bohr's Atomic Theory 1. Spectral Series |
| 第 3 週 | Bohr's Atomic Theory 1. Spectral Series |
| 第 4 週 | The Foundations of Quantum Mechanics 1. The Wave Nature of Electrons 2. Zero-Point The Uncertainty Principle |
| 第 4 週 | The Foundations of Quantum Mechanics 1. The Wave Nature of Electrons 2. Zero-Point The Uncertainty Principle |
| 第 5 週 | Schrodinger's Wave Mechanics 1. Eigenfunctions and Normalization |
| 第 5 週 | Schrodinger's Wave Mechanics 1. Eigenfunctions and Normalization |
| 第 6 週 | Schrodinger's Wave Mechanics 1. Eigenfunctions and Normalization |
| 第 6 週 | Schrodinger's Wave Mechanics 1. Eigenfunctions and Normalization |
| 第 7 週 | Quantum-Mechanical Postulates 1. Orthogonality of Wave Functions |
| 第 7 週 | Quantum-Mechanical Postulates 1. Orthogonality of Wave Functions |
| 第 8 週 | Quantum-Mechanical Postulates 1. Orthogonality of Wave Functions |
| 第 8 週 | Quantum-Mechanical Postulates 1. Orthogonality of Wave Functions |
| 第 9 週 | Quantum Mehanics of Some Simple Systems 1. The Free Particle 2. The Particle in a Box 3. The Harmonic Oscillator |
| 第 9 週 | Quantum Mehanics of Some Simple Systems 1. The Free Particle 2. The Particle in a Box 3. The Harmonic Oscillator |
| 第 10 週 | Mid-term Exam |
| 第 10 週 | Mid-term Exam |
| 第 11 週 | Quantum Mechanics of Hydrogenlike Atoms 1. Solution of the Equation 2. Solution of the Equation 3. Solution of the Solution of the R Equation 4. Complete Wave Functions |
| 第 11 週 | Quantum Mechanics of Hydrogenlike Atoms 1. Solution of the Equation 2. Solution of the Equation 3. Solution of the Solution of the R Equation 4. Complete Wave Functions |
| 第 12 週 | Quantum Mechanics of Hydrogenlike Atoms 1. Solution of the Equation 2. Solution of the Equation 3. Solution of the Solution of the R Equation 4. Complete Wave Functions |
| 第 12 週 | Quantum Mechanics of Hydrogenlike Atoms 1. Solution of the Equation 2. Solution of the Equation 3. Solution of the Solution of the R Equation 4. Complete Wave Functions |
| 第 13 週 | Physical Significance of the Orbital Quantum Numbers 1. The Principal Quantum Number n 2. Angular Dependence of the Wave Function: The Quantum Numbers ʅ and mʅ |
| 第 13 週 | Physical Significance of the Orbital Quantum Numbers 1. The Principal Quantum Number n 2. Angular Dependence of the Wave Function: The Quantum Numbers ʅ and mʅ |
| 第 14 週 | Angular Momentum and Magnetic Moment 1. Angular Momentum 2. Magnetic Moment |
| 第 14 週 | Angular Momentum and Magnetic Moment 1. Angular Momentum 2. Magnetic Moment |
| 第 15 週 | The Rigid Linear Rotor Spin Quantum Numbers |
| 第 15 週 | The Rigid Linear Rotor Spin Quantum Numbers |
| 第 16 週 | Many-Electron Atoms 1. The Aufbau Principle 2. The Pauli Exclusion Principle 3. Hund's Rule |
| 第 16 週 | Many-Electron Atoms 1. The Aufbau Principle 2. The Pauli Exclusion Principle 3. Hund's Rule |
| 第 17 週 | Approximation Method in Quantum Mechanics 1. The Variation Method 2. Perturbation Method 3. Slater Orbitals 4. Relativistic Effects in Quantum Mechanics 5. Key Equations |
| 第 17 週 | Approximation Method in Quantum Mechanics 1. The Variation Method 2. Perturbation Method 3. Slater Orbitals 4. Relativistic Effects in Quantum Mechanics 5. Key Equations |
| 第 18 週 | Approximation Method in Quantum Mechanics 1. The Variation Method 2. Perturbation Method 3. Slater Orbitals 4. Relativistic Effects in Quantum Mechanics 5. Key Equations |
| 第 18 週 | Approximation Method in Quantum Mechanics 1. The Variation Method 2. Perturbation Method 3. Slater Orbitals 4. Relativistic Effects in Quantum Mechanics 5. Key Equations |
| 第 19 週 | Final Exam |
| 第 19 週 | Final Exam |
教科書
Physical Cemistry 5e, K. J. Laidler, J. H. Meiser, and B. C. Sanctuary, Multi-Media Publicat, 2019